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Is the Thermal [4+2] Cycloaddition Between Allyl Anion and Ethylene

question 72

Essay

Is the thermal [4+2] cycloaddition between allyl anion and ethylene an allowed one? To answer, draw the HOMO of allyl anion and the LUMO of ethylene, and comment on the symmetry match of the two.

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Definitions:

Chlorine Atom

An elementary particle of chlorine, which is a chemical element with the symbol Cl and atomic number 17, known for its high reactivity and use as a disinfectant.

Ozone Molecules

Triatomic molecules consisting of three oxygen atoms, crucial for absorbing the majority of the sun's harmful ultraviolet radiation in the Earth's atmosphere.

Molecular Oxygen

A diatomic molecule composed of two oxygen atoms, O2, essential for most forms of life on Earth due to its role in cellular respiration.

Wildlife Habitats

Natural environments in which various species of wild plants, animals, fungi, and other organisms live and interact.

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