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How Could IR Spectroscopy Be Used to Distinguish Between the Following

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How could IR spectroscopy be used to distinguish between the following pair of compounds?
CH3CH2C How could IR spectroscopy be used to distinguish between the following pair of compounds? CH<sub>3</sub>CH<sub>2</sub>C    CH and CH<sub>3</sub>C    CCH<sub>3</sub>
CH and CH3C How could IR spectroscopy be used to distinguish between the following pair of compounds? CH<sub>3</sub>CH<sub>2</sub>C    CH and CH<sub>3</sub>C    CCH<sub>3</sub>
CCH3

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Definitions:

Delegator

A party in a contract who transfers his or her duties to perform to a third party who is not a part of the original contract (a delegatee).

Donee Beneficiary

A third party who benefits from a contract between two other parties, especially in cases involving the transfer of a gift or a donation.

Promisor

In a third-party beneficiary contract, the party to the contract who made the promise that benefits the third party.

Third-Party Beneficiary

An individual or entity that, though not a party to a contract, stands to benefit from its execution.

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