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The true sampling error is usually not known because
Stereogenic Centers
Atoms within a molecule that are bonded to four different substituents, giving rise to stereoisomerism.
Diastereomers
Stereoisomers that are not mirror images of each other and possess different physical and chemical properties.
Diastereomers
Stereoisomers that are not mirror images of each other, differing in the arrangement of atoms around one or more stereogenic centers.
Enantiomers
Molecules that are mirror images of each other and cannot be superimposed, similar to a pair of hands.
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