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Calculate E° Cell and Indicate Whether the Overall Reaction Shown

question 64

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Calculate E° cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous. O2(g) + 4H+(aq) + 4e-
Calculate E°<sub> cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous. O<sub>2</sub>(g)  + 4H<sup>+</sup>(aq)  + 4e<sup>-</sup> <sup> </sup>   2H<sub>2</sub>O(l)  E° = 1.229 V Al<sup>3+</sup>(aq)  + 3e<sup>-</sup> <sup> </sup>   Al(s)  E° = -1.662 V Overall reaction: 4Al(s)  + 3O<sub>2</sub>(g)  + 12H<sup>+</sup>(aq)  → 4Al<sup>3+</sup>(aq)  + 6H<sub>2</sub>O(l)  A)  E°<sub> cell</sub> = -2.891 V, nonspontaneous B)  E°<sub> cell</sub> = -2.891 V, spontaneous C)  E°<sub> cell</sub> = 2.891 V, nonspontaneous D)  E°<sub> cell</sub> = 2.891 V, spontaneous E)  None of these choices are correct. 2H2O(l) E° = 1.229 V
Al3+(aq) + 3e-
Calculate E°<sub> cell</sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous. O<sub>2</sub>(g)  + 4H<sup>+</sup>(aq)  + 4e<sup>-</sup> <sup> </sup>   2H<sub>2</sub>O(l)  E° = 1.229 V Al<sup>3+</sup>(aq)  + 3e<sup>-</sup> <sup> </sup>   Al(s)  E° = -1.662 V Overall reaction: 4Al(s)  + 3O<sub>2</sub>(g)  + 12H<sup>+</sup>(aq)  → 4Al<sup>3+</sup>(aq)  + 6H<sub>2</sub>O(l)  A)  E°<sub> cell</sub> = -2.891 V, nonspontaneous B)  E°<sub> cell</sub> = -2.891 V, spontaneous C)  E°<sub> cell</sub> = 2.891 V, nonspontaneous D)  E°<sub> cell</sub> = 2.891 V, spontaneous E)  None of these choices are correct. Al(s) E° = -1.662 V
Overall reaction:
4Al(s) + 3O2(g) + 12H+(aq) → 4Al3+(aq) + 6H2O(l)

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