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Electrochemical Cell Potentials Can Be Used to Determine Equilibrium Constants \rightarrow

question 43

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Electrochemical cell potentials can be used to determine equilibrium constants that would be otherwise difficult to determine because concentrations are small. Calculate the value of Ksp for CdS from the following data.
CdS(s) + 2e- \rightarrow Cd(s) + S2-(aq)
E° = -1.21 V
Cd2+(aq) + 2e- \rightarrow Cd(s)
E° = -0.40 V


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