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A mining operation needs to separate silver and copper. You are hired as a summer intern in a beautiful Colorado mining town, and one of your tasks is to determine whether this separation can be accomplished by oxidizing the metals to Ag+ and Cu+, each one at a concentration of 0.15 M, and then precipitating one as the chloride salt without precipitating the other. AgCl precipitates first. What is the concentration of the Ag+ remaining in solution when CuCl begins to precipitate? For AgCl, pKsp = 9.74, and for CuCl, pKsp = 6.76.
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