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At 25 \circ C, the Following Heats of Reaction Are Known

question 97

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At 25 \circ C, the following heats of reaction are known: 2ClF( g) +O2( g) Cl2O( g) +F2O( g) ΔHrxn=167.4 kJ/mol2ClF3( g) +2O2( g) Cl2O( g) +3 F2O( g) ΔHrxn=341.4 kJ/mol2 F2( g) +O2( g) 2 F2O( g) ΔHrxn=43.4 kJ/mol\begin{array}{ll}2 \mathrm{ClF}(\mathrm{~g}) +\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}_{2} \mathrm{O}(\mathrm{~g}) +\mathrm{F}_{2} \mathrm{O}(\mathrm{~g}) & \Delta \mathrm{H}_{\mathrm{rxn}}^{\circ}=167.4 \mathrm{~kJ} / \mathrm{mol} \\2 \mathrm{ClF}_{3}(\mathrm{~g}) +2 \mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}_{2} \mathrm{O}(\mathrm{~g}) +3 \mathrm{~F}_{2} \mathrm{O}(\mathrm{~g}) & \Delta \mathrm{H}_{\mathrm{rxn}}^{\circ}=341.4 \mathrm{~kJ} / \mathrm{mol} \\2 \mathrm{~F}_{2}(\mathrm{~g}) +\mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{~F}_{2} \mathrm{O}(\mathrm{~g}) & \Delta \mathrm{H}_{\mathrm{rxn}}^{\circ}=-43.4 \mathrm{~kJ} / \mathrm{mol}\end{array} At the same temperature, use the above data to calculate the heat released (kJ) when 3.40 moles of ClF(g) reacts with excess F2: ClF(g) + F2(g) \rarr ClF3(g)


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