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In order to determine the identity of a particular transition metal (M) ,a voltaic cell is constructed at 25°C with the anode consisting of the transition metal as the electrode immersed in a solution of 0.0977 M M(NO3) 2,and the cathode consisting of a copper electrode immersed in a 0.0724M Cu(NO3) 2 solution.The two half-reactions are as follows:
M(s) M2+(aq) + 2e-
Cu2+(aq) + 2e- Cu(s)
The potential measured across the cell is 1.13 V.What is the identity of the metal M?
Reduction Half-Reaction
E° (V)
Cu2+(aq) + 2e- Cu(s) +0.34
Ni2+(aq) + 2e- Ni(s) -0.23
Cd2+(aq) + 2e- Cd(s) - 0.40
Zn2+(aq) + 2e- Zn(s) -0.76
Mn2+(aq) + 2e- Mn(s) -1.18
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