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A 0.535 g sample of pyrolusite ore (impure MnO2) is treated with 1.42 g oxalic acid (H2C2O4 ∙ 2H2O) in an acidic medium.Following this reaction,the excess oxalic acid is titrated with 0.1000 M KMnO4,36.6 mL being required.What is the % MnO2 in the ore? The reactions are:
H2C2O4 ∙ 2 H2O(aq) + MnO2(s) + 2 H+(aq) → Mn2+(aq) + 4 H2O(l) + 2 CO2(g)
5 H2C2O4 ∙ 2H2O(aq) + 2 MnO4-(aq) + 6 H+(aq) → 2 Mn2+(aq) + 18 H2O(l) + 10 CO2(g)
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