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Which Sequence of Reactions Is Expected to Produce the Product

question 172

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Which sequence of reactions is expected to produce the product below as the final, and major, organic product? Which sequence of reactions is expected to produce the product below as the final, and major, organic product?   I 1. HC≡CH, NaNH<sub>2</sub>; 2. (CH<sub>3</sub>) <sub>2</sub>CHCH<sub>2</sub>Br 3. Aqueous H<sub>2</sub>SO<sub>4</sub>, HgSO<sub>4</sub> II 1. CH<sub>3</sub>C≡CH, NaNH<sub>2</sub>; 2. (CH<sub>3</sub>) <sub>2</sub>CHBr; 3. Disisamylborane; 4. H<sub>2</sub>O<sub>2</sub>, NaOH III 1. (CH<sub>3</sub>) <sub>2</sub>CHBr, NaNH<sub>2</sub>; 2. CH<sub>3</sub>C≡CH; 3. O<sub>3</sub>; 4. H<sub>2</sub>O IV 1. CH<sub>3</sub>C≡CH, NaNH<sub>2</sub>: 2. (CH<sub>3</sub>) <sub>2</sub>CHCH<sub>2</sub>Br; 3. BH<sub>3</sub>●THF; 4. H<sub>2</sub>O<sub>2</sub>, NaOH V 1)  (CH<sub>3</sub>) <sub>2</sub>CHCH<sub>2</sub>Br, NaNH<sub>2</sub>; 2. HC≡CH; 3. 9-BBN; 4. H<sub>2</sub>O<sub>2</sub>, NaOH A)  I B)  II C)  III D)  IV E)  V I 1. HC≡CH, NaNH2; 2. (CH3) 2CHCH2Br 3. Aqueous H2SO4, HgSO4 II 1. CH3C≡CH, NaNH2; 2. (CH3) 2CHBr; 3. Disisamylborane; 4. H2O2, NaOH
III 1. (CH3) 2CHBr, NaNH2; 2. CH3C≡CH; 3. O3; 4. H2O
IV 1. CH3C≡CH, NaNH2: 2. (CH3) 2CHCH2Br; 3. BH3●THF; 4. H2O2, NaOH
V 1) (CH3) 2CHCH2Br, NaNH2; 2. HC≡CH; 3. 9-BBN; 4. H2O2, NaOH


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