A Carbonyl,the C

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A Carbonyl,the C

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The Answer is The point of difference in the three structures is the substitution on the carbon of the carbonyl.Any property that influences electron distribution will influence the magnitude of the positive charge.Effects are either electron withdrawing (e.g.,an electronegative atom)or electron donating (e.g.,compare the Pauling electronegativity values and resonance potential of each atom).The carbonyl carbon of the acyl chloride has the greatest partial positive charge.There are three lone pairs on Cl and two on the O of the OH.Because one of the oxygen lone pairs can be delocalized through resonance,electron density is added to the C

The point of difference in the three structures is the substitution on the carbon of the carbonyl.Any property that influences electron distribution will influence the magnitude of the positive charge.Effects are either electron withdrawing (e.g.,an electronegative atom)or electron donating (e.g.,compare the Pauling electronegativity values and resonance potential of each atom).The carbonyl carbon of the acyl chloride has the greatest partial positive charge.There are three lone pairs on Cl and two on the O of the OH.Because one of the oxygen lone pairs can be delocalized through resonance,electron density is added to the C O,and the partial positive charge of the carbonyl carbon is reduced.Given that Cl does not typically engage in resonance,then the electron withdrawing nature of the electronegative Cl predominates.

O,and the partial positive charge of the carbonyl carbon is reduced.Given that Cl does not typically engage in resonance,then the electron withdrawing nature of the electronegative Cl predominates.

A Carbonyl,the C

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