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At some temperatures,the relative reactivities of 3°,2° and 1° alkane hydrogens in free radical chlorination are in the ratio of 5:3:1.Thus,monochlorination of isopentane should produce these percentages of 2-chloro-2-methylbutane (A) ,combined 1-chloro-2-methylbutane and 1-chloro-3-methylbutane (B) ,and 2-chloro-3-methylbutane (C) :
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