The Migratory Aptitude for Groups Attached to a Ketone or Aldehyde

question 62

Multiple Choice

The migratory aptitude for groups attached to a ketone or aldehyde carbonyl during the Baeyer-Villiger oxidation is:

• A)H > Ph- > 3° alkyl > 2° alkyl > 1° alkyl > methyl
• B)Ph- > H > 3° alkyl >2° alkyl >1° alkyl > methyl
• C)3° alkyl > 2° alkyl > 1° alkyl > methyl > H > Ph-
• D)3° alkyl > 2° alkyl > 1° alkyl > methyl > Ph- >H
• E)H > 3° alkyl > 2° alkyl > 1° alkyl > methyl >Ph-

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