Examlex
When ethyl acetoacetate is treated with one equivalent of ethoxide ion followed by one equivalent of 1,2-dibromoethane compound,X is produced.Treatment of X with a second equivalent of ethoxide,produces Y.Further treatment of this product to conditions of saponification,acidification and heating produced a product,Z,that gives the following spectral data:
1H NMR: 0.88 multiplet 13C NMR: Broad Band Decoupled: 10.40,21.17,29.84,
208.30
1.00 multiplet DEPT 90: 21.17
1.96 multiplet DEPT 135: positive signals at 21.17,29.84
2.24 singlet negative signals at 10.40
What is a reasonable structure for Z?
Q17: What product results from the intramolecular aldol
Q25: Complete the following reaction sequence,giving structural details
Q28: Choose the reagent(s)that would bring about
Q54: Which compound would be the strongest acid?<br>A)CHCl<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CO<sub>2</sub>H<br>B)ClCH<sub>2</sub>CHClCH<sub>2</sub>CO<sub>2</sub>H<br>C)CH<sub>3</sub>CCl<sub>2</sub>CH<sub>2</sub>CO<sub>2</sub>H<br>D)CH<sub>3</sub>CHClCHClCO<sub>2</sub>H<br>E)CH<sub>3</sub>CH<sub>2</sub>CCl<sub>2</sub>CO<sub>2</sub>H
Q58: A reaction of a particular
Q59: The aldol reaction of cyclohexanone produces which
Q86: What reagent would help you distinguish between
Q160: What is the reactant of the following
Q171: The correct structure of bicyclo[1.1.0]butan-2-amine is? <img
Q174: When <img src="https://d2lvgg3v3hfg70.cloudfront.net/TB5902/.jpg" alt="When cyclizes