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A phosphate buffer solution (25.00 mL sample) used for a growth medium was titrated with 0.1000 M hydrochloric acid. The components of the buffer were sodium monohydrogen phosphate and sodium dihydrogen phosphate. The first endpoint occurred at a volume of 10.32 mL; the second occurred after an additional 18.62 mL was added, for a total volume of 28.94 mL. What was the approximate ratio of HPO42 to H2PO4 in the buffer?
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