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Cu2+ + 2e- → Cu(s) E° = 0.34 V
V2+ + 2e- → V(s) E° = -1.20 V
In a galvanic cell, the copper compartment contains a copper electrode and [Cu2+] = 1.00 M. The vanadium compartment contains a vanadium electrode and V2+ at an unknown concentration. The compartment containing the vanadium (1.00 L of solution) was titrated with 0.0800 M H2EDTA2-, resulting in the reaction:
H2EDTA2- + V2+ VEDTA2- + 2H+
The potential of the cell was monitored to determine the stoichiometric point for the process, which occurred when 500.0 mL of H2EDTA2- solution was added. At the stoichiometric point, Ecell was 1.98 V. The solution was buffered at pH 10.00.A. Calculate Ecell before titration was carried out.B. Calculate the equilibrium constant K for the titration reaction.C. Calculate Ecell at the halfway point of titration.
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