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As O2(l) Is Cooled at 1 Atm, It Freezes at 54.5

question 42

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As O2(l) is cooled at 1 atm, it freezes at 54.5 K to form Solid I. At a lower temperature, Solid I rearranges to Solid II, which has a different crystal structure. Thermal measurements show that ΔH for the I → II phase transition is -743.1 J/mol and that ΔS for the same transition is -17.0 J/K mol. At what temperature are Solids I and II in equilibrium?


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