Solution Volumes an Analytical Chemist Wanted to Use Electrolysis to Determine the Determine

question 27

Essay

Solution Volumes
An analytical chemist wanted to use electrolysis to determine the number of moles of cupric ions in a given volume of solution. The solution was partitioned into n = 30 portions of 0.2 mL each. Each of the n = 30 portions was tested. The average number of moles of cupric ions for the n = 30 portions was found to be 0.185 mole; the standard deviation was 0.015 mole.
-Refer to the Solution Volumes statement. Suppose the chemist had used only n = 5 portions of the solution for the experiment and obtained the readings 0.18, 0.21, 0.20, 0.22, and 0.18. Would the Empirical Rule be suitable for describing the n = 5 measurements? Why?

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