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Dinitrogen Tetroxide Decomposes to Form Nitrogen Dioxide in a Second-Order

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Dinitrogen tetroxide decomposes to form nitrogen dioxide in a second-order reaction:
N2O4(g) → 2NO2(g)
At 400.0 K,the rate constant for this reaction has been measured to be 2.9 × 108 L/(mol ∙ s) .Suppose 0.742 mol of N2O4(g) is placed in a sealed 34.3-L container at 400.0 K and allowed to react.What is the total pressure inside the vessel after 49.6 ns has elapsed? (R= 0.0821 (L ∙ atm) /(K ∙ mol) )


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